Heksafluoroacetilacetonatni kompleksi kadmija(II) s amidnim derivatima piridina. Keto-enolna tautomerija i nastava kemije

Bukvić, Kristina

prikaz prve stranice dokumenta Heksafluoroacetilacetonatni kompleksi kadmija(II) s amidnim derivatima piridina. Keto-enolna tautomerija i nastava kemije

master's thesis

Heksafluoroacetilacetonatni kompleksi kadmija(II) s amidnim derivatima piridina. Keto-enolna tautomerija i nastava kemije

Zagreb: University of Zagreb, Faculty of Science, 2017. urn:nbn:hr:217:832857

Bukvić, Kristina

University of Zagreb
Faculty of Science
Department of Biology
University of Zagreb
Faculty of Science
Department of Chemistry

Cite this document

APA 6th Edition

Bukvić, K. (2017). Heksafluoroacetilacetonatni kompleksi kadmija(II) s amidnim derivatima piridina. Keto-enolna tautomerija i nastava kemije (Master's thesis). Zagreb: University of Zagreb, Faculty of Science; Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:832857

MLA 8th Edition

Bukvić, Kristina. "Heksafluoroacetilacetonatni kompleksi kadmija(II) s amidnim derivatima piridina. Keto-enolna tautomerija i nastava kemije." Master's thesis, University of Zagreb, Faculty of Science; University of Zagreb, Faculty of Science, 2017. https://urn.nsk.hr/urn:nbn:hr:217:832857

Chicago 17th Edition

Harvard

Bukvić, K. (2017). 'Heksafluoroacetilacetonatni kompleksi kadmija(II) s amidnim derivatima piridina. Keto-enolna tautomerija i nastava kemije', Master's thesis, University of Zagreb, Faculty of Science; University of Zagreb, Faculty of Science, accessed 18 April 2024, https://urn.nsk.hr/urn:nbn:hr:217:832857

Vancouver

Bukvić K. Heksafluoroacetilacetonatni kompleksi kadmija(II) s amidnim derivatima piridina. Keto-enolna tautomerija i nastava kemije [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; Zagreb: University of Zagreb, Faculty of Science; 2017 [cited 2024 April 18] Available at: https://urn.nsk.hr/urn:nbn:hr:217:832857

IEEE

K. Bukvić, "Heksafluoroacetilacetonatni kompleksi kadmija(II) s amidnim derivatima piridina. Keto-enolna tautomerija i nastava kemije", Master's thesis, University of Zagreb, Faculty of Science, Zagreb; University of Zagreb, Faculty of Science, Zagreb, 2017. Available at: https://urn.nsk.hr/urn:nbn:hr:217:832857

Cite this item: https://urn.nsk.hr/urn:nbn:hr:217:832857

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Metadata

Title	Heksafluoroacetilacetonatni kompleksi kadmija(II) s amidnim derivatima piridina. Keto-enolna tautomerija i nastava kemije
Title (english)	Hexafluoroacetylacetonato complexes of cadmium(II) with amide derivatives of pyridine. Keto-enol tautomerism and teaching chemistry
Author	Kristina Bukvić
Mentor	Marijana Đaković (mentor)
Mentor	Nenad Judaš (mentor)
Committee member	Marijana Đaković (predsjednik povjerenstva)
Committee member	Nenad Judaš (član povjerenstva)
Committee member	Jasna Lajtner (član povjerenstva)
Committee member	Mirela Sertić Perić (član povjerenstva)
Granter	University of Zagreb Faculty of Science (Department of Biology) Zagreb
Granter	University of Zagreb Faculty of Science (Department of Chemistry) Zagreb
Defense date and country	2017-12-14, Croatia
Scientific / art field, discipline and subdiscipline	NATURAL SCIENCES Biology
Abstract	Ovaj diplomski rad sastoji se od dvije cjeline: istraživačkog i metodičkog dijela. U istraživačkom dijelu sintetizirani su heksafluoroacetilacetonatni (hfac) kompleksi kadmija(II) s N-(piridin-3- il)propanamidom (3-propy), N-(piridin-3-il)etanamidom (3-acpy), N-(piridin-4-il)propanamidom (4- propy) i N-(piridin-4-il)etanamidom (4-acpy). Spojevi su priređeni klasičnim otopinskim i mehanokemijskim sintetskim postupcima. Kompleksi su okarakterizirani IR spektroskopijom, metodom rentgenske difrakcije u polikristalnom uzorku i termogravimetrijskom analizom. Difrakcijom rentgenskih zraka u jediničnom kristalu određena je molekulska i kristalna struktura spoja [Cd(hfac)2(3-propy)2]. Ustanovljeno je da su mehanokemijski postupci priprave ove klase liganada kao i koordinacijskih spojeva pogodniji u odnosu na klasičnu otopinsku sintezu. U metodičkom dijelu rada osmišljen je prijedlog nastavnog sata na temu „Keto-enolna tautomerija”. Prijedlog nastavnog sata namijenjen je završnom razredu gimnazijskog smjera, a temelji se na strategiji učenja otkrivanjem. Učenici trebaju biti dobro pripremljeni za ovakav nastavni sat (navedeni su nužni ulazni obrazovni ishodi) i vještine u izvođenju pokusa.
Abstract (english)	This Diploma thesis consists of two parts: the research part and the methodical part. In the research part a series of hexafluoroacetyacetonato (hfac) cadmium(II) coordination compounds N-(pyridin-3- yl)propionamide (3-propy), N-(pyridin-3-yl)acetamide (3-acpy), N-(pyridin-4-yl)propionamide (4- propy) i N-(pyridin-4-yl)acetamide (4-acpy) were prepared. The compounds were synthesized by classical solution and mechanochemical synthetic procedures and characterized by infrared spectroscopy, PXRD methods and thermal analysis. Molecular and crystal structure of the compound [Cd(hfac)2(3-propy)2] was determined by single crystal X-ray structure analysis. It has been found that the mechanochemical synthetic procedures are more suitable for the preparation of this class of ligands as well as coordination compounds than the classical solution synthesis. In the methodical part of the thesis, a teaching lesson is designed that deals with Keto-enol tautomerism. The proposed lesson may be applied at the end of high school course of organic chemistry and is based on the strategy of inquiry learning with special emphasis on the use of experiment. Students should be well prepared and skilled in experimental work.
Keywords
Keywords (english)
Language	croatian
URN:NBN	urn:nbn:hr:217:832857
Study programme	Title: Integrated undergraduate and graduate university study of Biology and Chemistry Education; specializations in: Integrated undergraduate and graduate university study of Biology and Chemistry Education Course: Integrated undergraduate and graduate university study of Biology and Chemistry Education Study programme type: university Study level: integrated undergraduate and graduate Academic / professional title: magistar/magistra edukacije biologije i kemije (magistar/magistra edukacije biologije i kemije)
Type of resource	Text
File origin	Born digital
Access conditions	Open access
Terms of use
Repository	Repository of the Faculty of Science
Created on	2018-01-31 09:48:10

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