Sinteza i karakterizacija kompleksa [MoO2L(D)] (L = nesimetrična Schiffova baza, D = dušikova baza ili metanol)

Bilić, Luka

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master's thesis

Sinteza i karakterizacija kompleksa [MoO2L(D)] (L = nesimetrična Schiffova baza, D = dušikova baza ili metanol)

Zagreb: University of Zagreb, Faculty of Science, 2016. urn:nbn:hr:217:818446

Bilić, Luka

University of Zagreb
Faculty of Science
Department of Chemistry

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APA 6th Edition

Bilić, L. (2016). Sinteza i karakterizacija kompleksa [MoO2L(D)] (L = nesimetrična Schiffova baza, D = dušikova baza ili metanol) (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:818446

MLA 8th Edition

Bilić, Luka. "Sinteza i karakterizacija kompleksa [MoO2L(D)] (L = nesimetrična Schiffova baza, D = dušikova baza ili metanol)." Master's thesis, University of Zagreb, Faculty of Science, 2016. https://urn.nsk.hr/urn:nbn:hr:217:818446

Chicago 17th Edition

Harvard

Bilić, L. (2016). 'Sinteza i karakterizacija kompleksa [MoO2L(D)] (L = nesimetrična Schiffova baza, D = dušikova baza ili metanol)', Master's thesis, University of Zagreb, Faculty of Science, accessed 19 April 2024, https://urn.nsk.hr/urn:nbn:hr:217:818446

Vancouver

Bilić L. Sinteza i karakterizacija kompleksa [MoO2L(D)] (L = nesimetrična Schiffova baza, D = dušikova baza ili metanol) [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2016 [cited 2024 April 19] Available at: https://urn.nsk.hr/urn:nbn:hr:217:818446

IEEE

L. Bilić, "Sinteza i karakterizacija kompleksa [MoO2L(D)] (L = nesimetrična Schiffova baza, D = dušikova baza ili metanol)", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2016. Available at: https://urn.nsk.hr/urn:nbn:hr:217:818446

Cite this item: https://urn.nsk.hr/urn:nbn:hr:217:818446

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Title	Sinteza i karakterizacija kompleksa [MoO2L(D)] (L = nesimetrična Schiffova baza, D = dušikova baza ili metanol)
Title (english)	Synthesis and characterization of metal complexes [MoO2L(D)] (L = asymmetric Schiff base, D = O- or N- donor ligand)
Author	Luka Bilić
Mentor	Marina Cindrić (mentor)
Committee member	Marina Cindrić (predsjednik povjerenstva)
Committee member	Davor Kovačević (član povjerenstva)
Committee member	Višnja Vrdoljak (član povjerenstva)
Committee member	Ines Primožič (član povjerenstva)
Granter	University of Zagreb Faculty of Science (Department of Chemistry) Zagreb
Defense date and country	2016-03-03, Croatia
Scientific / art field, discipline and subdiscipline	NATURAL SCIENCES Chemistry
Abstract	U okviru ovog diplomskog rada priređeni su momonuklearni oktaedarski kompleksi molibdena(VI) opće formule [MoO2L(D)] (D = MeOH, py, 3-Mepy i 4-Mepy); (1-8) diknuklearni kompleksi molibdena (VI) opće formule [MoO2L]2(4,4-bipy); (9-10) i polinuklearni kompleksi molibdena(VI) opće formule [MoO2L]n; (11-12). Svi priređeni spojevi sadrže cis-MoO22+ jezgru na koju je kao tridentatni O,N,O donorski ligand vezana jedna nesimetrična Schiffova baza, L = 3-((2-hidroksi-4-metilfenil)amino)-1-fenilbut-2-en-1-on ili 3-((2-hidroksi-5-metilfenil)amino)-1-fenilbut-2-en-1-on. Na 6. koordinacijsko mjesto tj. u trans položaju u odnosu na terminalni kisikov atom je vezana kao N ili O donor neutralna molekula Lewisove baze. Na priređenim mononuklearnim kompleksima ispitivane su reakcije izmjene liganada vezanih na šesto koordinacijsko mjesto. Reakcije su provedene u otopini i u čvrstom stanju. Svi novopriređeni spojevi su okarakterizirani na temelju podataka dobivenih iz infracrvenih spekta
Abstract (english)	In this thesis novel mononuclear octahedral complexes of molybdenum(VI) [MoO2L(D)] (D = MeOH, py, 3-Mepy and 4-Mepy); (1-8), dinuclear complexes of molybdenum(VI) [MoO2L]2(4,4-bipy); (9-10) and polynuclear complexes of molybdenum(VI) [MoO2L]n; (11-12) were prepared. All prepared complexes contain cis-MoO22+ moiety on which asymmetric Schiff base, L= 3-((2-hydroxy-4-methylphenyl)amino)-1-phenylbuth-2-ene-1-one or 3-((2-hydroxy-5-methylphenyl)amino)-1-phenylbuth-2-ene-1-one, is coordinated as a tridentate O,N,O donor ligand. The 6th coordination place in trans position with respect to the terminal oxygen atom is occupied by a neutral molecule N- or O- donor Lewis base. The substitution of ligands on 6th coordination place was studied for mononuclear molybdenum(VI) complexes (1-8). Substitution reactions were performed both solvent-free and in solution. All prepared complexes were studied by infrared spectroscopy, chemical and thermal analysis and their structures were determined by X-ray crystallography.
Keywords
Keywords (english)
Language	croatian
URN:NBN	urn:nbn:hr:217:818446
Study programme	Title: Graduate university studies in chemistry; specializations in: Research programme Course: Research programme Study programme type: university Study level: graduate Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resource	Text
File origin	Born digital
Access conditions	Open access Embargo expiration date: 2018-03-03
Terms of use
Repository	Repository of the Faculty of Science
Created on	2017-03-14 14:47:24

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