Sinteza i strukturna karakterizacija kompleksa kobalta(II) i nikla(II) s amidima glicina

Kirasić, Inka

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master's thesis

Sinteza i strukturna karakterizacija kompleksa kobalta(II) i nikla(II) s amidima glicina

Zagreb: University of Zagreb, Faculty of Science, 2017. urn:nbn:hr:217:519664

Kirasić, Inka

University of Zagreb
Faculty of Science
Department of Chemistry

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APA 6th Edition

Kirasić, I. (2017). Sinteza i strukturna karakterizacija kompleksa kobalta(II) i nikla(II) s amidima glicina (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:519664

MLA 8th Edition

Kirasić, Inka. "Sinteza i strukturna karakterizacija kompleksa kobalta(II) i nikla(II) s amidima glicina." Master's thesis, University of Zagreb, Faculty of Science, 2017. https://urn.nsk.hr/urn:nbn:hr:217:519664

Chicago 17th Edition

Harvard

Kirasić, I. (2017). 'Sinteza i strukturna karakterizacija kompleksa kobalta(II) i nikla(II) s amidima glicina', Master's thesis, University of Zagreb, Faculty of Science, accessed 16 April 2024, https://urn.nsk.hr/urn:nbn:hr:217:519664

Vancouver

Kirasić I. Sinteza i strukturna karakterizacija kompleksa kobalta(II) i nikla(II) s amidima glicina [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2017 [cited 2024 April 16] Available at: https://urn.nsk.hr/urn:nbn:hr:217:519664

IEEE

I. Kirasić, "Sinteza i strukturna karakterizacija kompleksa kobalta(II) i nikla(II) s amidima glicina", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2017. Available at: https://urn.nsk.hr/urn:nbn:hr:217:519664

Cite this item: https://urn.nsk.hr/urn:nbn:hr:217:519664

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Title	Sinteza i strukturna karakterizacija kompleksa kobalta(II) i nikla(II) s amidima glicina
Title (english)	Synthesis and structural characterization of cobalt(II) and nickel(II) complexes with glycine amides
Author	Inka Kirasić
Mentor	Biserka Prugovečki (mentor)
Mentor	Draginja Mrvoš-Sermek (mentor)
Committee member	Biserka Prugovečki (predsjednik povjerenstva)
Committee member	Draginja Mrvoš-Sermek (član povjerenstva)
Committee member	Vesna Petrović Peroković (član povjerenstva)
Committee member	Iva Juranović Cindrić (član povjerenstva)
Committee member	Dubravka Matković-Čalogović (član povjerenstva)
Granter	University of Zagreb Faculty of Science (Department of Chemistry) Zagreb
Defense date and country	2017-09-21, Croatia
Scientific / art field, discipline and subdiscipline	NATURAL SCIENCES Chemistry
Abstract	Ovaj diplomski rad sastoji se od dva dijela, istraživačkog i metodičkog. U istraživačkom dijelu sintetizirani su i strukturno okarakterizirani spojevi kobalta(II) i nikla(II) s 2,2'- iminodiacetamidom (idaa) te glicinamid hidrojodid (HGlyam)+I−. Sintetizirana su četiri nova spoja: (HGlyam)+I−, CoCl2(H2O)(idaa)2, Co(idaa)2I3I i Ni(idaa)2I3I. Sve sinteze su provedene u vodenom mediju pri sobnoj temperaturi. Metodom difrakcije rendgenskog zračenja na jediničnom kristalu riješene su molekulske i kristalne strukture novosintetiziranih spojeva te su spojevi dodatno karakterizirani metodom difrakcije rendgenskog zračenja na polikristalnom uzorku. Ustanovljeno je da su spojevi Co(idaa)2I3I i Ni(idaa)2I3I izostrukturni. U svim istraživanim kompleksnim spojevima metalni kationi su oktaedarski koordinirani. U metodičkom dijelu je dan prijedlog za učenički mini-projekt kojim se dokazuju cijanidi u gorkim bademima. Opisan je nastavni dvosat u okviru mini-projekta te su predloženi radni listić za učenike i uputa za nastavnike temeljena na učenju otkrivanjem.
Abstract (english)	This diploma thesis is composed of two parts, the research part and the methodological part. In the research part complex compounds of cobalt(II) and nickel(II) with 2,2’- iminodiacetamide (idaa) and glycinamide hydroiodide (HGlyam)+I− were synthesized and structurally characterized. Four new compounds were synthesized: (HGlyam)+I−, CoCl2(H2O)(idaa)2, Co(idaa)2I3I and Ni(idaa)2I3I. All syntheses were made in an aqueous medium at room temperature. Crystal and molecular structures of new compounds were solved by single-crystal X-ray diffraction and compounds were additionally analyzed by powder X-ray diffraction. It was found that compounds Co(idaa)2I3I and Ni(idaa)2I3I are isostructural. In all researched complexes the metal ions are octahedrally coordinated. In the methodological part a students' mini-project for detection of cyanide in bitter almonds was proposed. Two school hours were described within the mini-project. Examples of worksheets for students and guidance for teachers based on discovery learning are also included.
Keywords
Keywords (english)
Language	croatian
URN:NBN	urn:nbn:hr:217:519664
Study programme	Title: Graduate university studies in chemistry; specializations in: Educational programme Course: Educational programme Study programme type: university Study level: graduate Academic / professional title: magistar/magistra edukacije kemije (magistar/magistra edukacije kemije)
Type of resource	Text
File origin	Born digital
Access conditions	Open access Embargo expiration date: 2018-09-21
Terms of use
Repository	Repository of the Faculty of Science
Created on	2017-10-17 16:48:36

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