Utjecaj nekovalentnih interakcija na strukturu i svojstva koordinacijskih polimera kadmija(II) s halogeniranim piridinima i pirimidinima

Popov, Nina

prikaz prve stranice dokumenta Utjecaj nekovalentnih interakcija na strukturu i svojstva koordinacijskih polimera kadmija(II) s halogeniranim piridinima i pirimidinima

master's thesis

Utjecaj nekovalentnih interakcija na strukturu i svojstva koordinacijskih polimera kadmija(II) s halogeniranim piridinima i pirimidinima

Zagreb: University of Zagreb, Faculty of Science, 2018. urn:nbn:hr:217:895026

Popov, Nina

University of Zagreb
Faculty of Science
Department of Chemistry

Cite this document

APA 6th Edition

Popov, N. (2018). Utjecaj nekovalentnih interakcija na strukturu i svojstva koordinacijskih polimera kadmija(II) s halogeniranim piridinima i pirimidinima (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:895026

MLA 8th Edition

Popov, Nina. "Utjecaj nekovalentnih interakcija na strukturu i svojstva koordinacijskih polimera kadmija(II) s halogeniranim piridinima i pirimidinima." Master's thesis, University of Zagreb, Faculty of Science, 2018. https://urn.nsk.hr/urn:nbn:hr:217:895026

Chicago 17th Edition

Harvard

Popov, N. (2018). 'Utjecaj nekovalentnih interakcija na strukturu i svojstva koordinacijskih polimera kadmija(II) s halogeniranim piridinima i pirimidinima', Master's thesis, University of Zagreb, Faculty of Science, accessed 19 April 2024, https://urn.nsk.hr/urn:nbn:hr:217:895026

Vancouver

Popov N. Utjecaj nekovalentnih interakcija na strukturu i svojstva koordinacijskih polimera kadmija(II) s halogeniranim piridinima i pirimidinima [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2018 [cited 2024 April 19] Available at: https://urn.nsk.hr/urn:nbn:hr:217:895026

IEEE

N. Popov, "Utjecaj nekovalentnih interakcija na strukturu i svojstva koordinacijskih polimera kadmija(II) s halogeniranim piridinima i pirimidinima", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2018. Available at: https://urn.nsk.hr/urn:nbn:hr:217:895026

Cite this item: https://urn.nsk.hr/urn:nbn:hr:217:895026

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Metadata

Title	Utjecaj nekovalentnih interakcija na strukturu i svojstva koordinacijskih polimera kadmija(II) s halogeniranim piridinima i pirimidinima
Title (english)	Influence of the non-covalent interactions on structure and properties of cadmium(II) coordination polymers with halogen substituted pyridine and pyrimidine
Author	Nina Popov
Mentor	Željka Soldin (mentor)
Committee member	Željka Soldin (predsjednik povjerenstva)
Committee member	Iva Juranović Cindrić (član povjerenstva)
Committee member	Vesna Petrović Peroković (član povjerenstva)
Committee member	Marijana Đaković (član povjerenstva)
Granter	University of Zagreb Faculty of Science (Department of Chemistry) Zagreb
Defense date and country	2018-02-23, Croatia
Scientific / art field, discipline and subdiscipline	NATURAL SCIENCES Chemistry
Abstract	Ispitana je mogućnost priprave koordinacijskih polimera kadmijevih(II) halogenida s 5-brompirimidinom (5-Brpm) i 3-brompiridinom (3-Brpy). Pripravljeni su sljedeći spojevi [CdCl2(5-Brpm)2]n (1), [CdCl2(5-Brpm)]n (2), [CdBr2(5-Brpm)2]n (3), [CdBr2(5-Brpm)]n (4), [CdI2(5-Brpm)2]n (5), [CdI2(5-Brpm)]n (6), [CdCl2(3-Brpy)2]n (7), [CdCl2(3-Brpy)]n (8), [CdBr2(3-Brpy)2]n (9), [CdBr2(3-Brpy)]n (10), [CdI2(3-Brpy)2]n (11) i [CdI2(3-Brpy)]n (12). Spojevi su okarakterizirani kemijskom analizom, infracrvenom spektroskopijom, difrakcijom rentgenskog zračenja na polikristalnom uzorku i metodama termičke analize (TGA/SDTA). Spojevima 1, 3 i 5 je rentgenskom strukturnom analizom određena molekulska i kristalna struktura. Premosnim vezanjem halogenidnih iona nastaju 1D-koordinacijski polimeri s oktaedarski koordiniranim kadmijevim(II) ionima, koji se vodikovim i halogenskim vezama povezuju u supramolekulsku 3D mrežu. Istražena je mehanički uzrokovana fleksibilnost kristala pripravljenih spojeva. Kristali spojeva 1, 3 i 7 su kod djelovanja vanjske mehaničke sile pokazali elastična, a kristali spojeva 9 i 11 plastična svojstva.
Abstract (english)	The reactions of cadmium(II) halides with 3-bromopyridine and 5-bromopyrimidine were investigated. Following coordination polymers were prepared [CdCl2(5-Brpm)2]n (1), [CdCl2(5-Brpm)]n (2), [CdBr2(5-Brpm)2]n (3), [CdBr2(5-Brpm)]n (4), [CdI2(5-Brpm)2]n (5), [CdI2(5-Brpm)]n (6), [CdCl2(3-Brpy)2]n (7), [CdCl2(3-Brpy)]n (8), [CdBr2(3-Brpy)2]n (9), [CdBr2(3-Brpy)]n (10), [CdI2(3-Brpy)2]n (11) and [CdI2(3-Brpy)]n (12). All compounds were characterized by chemical analysis, infrared spectroscopy, X-ray diffraction and thermal analysis (TGA/SDTA). Single crystal X-ray structure determination of the compounds 1, 3 and 5 revealed 1D-coordination polymers comprised of halide-bridged Cd(II) octahedra. The building units are assembled into supramolecular 3D frameworks via a combination of hydrogen and halogen bonds. Mechanically induced flexibility of the crystals was investigated. Crystals of the compounds 1, 3 and 7 showed elastic and crystals of the compounds 7 and 11 plastic properties.
Keywords
Keywords (english)
Language	croatian
URN:NBN	urn:nbn:hr:217:895026
Study programme	Title: Graduate university studies in chemistry; specializations in: Research programme Course: Research programme Study programme type: university Study level: graduate Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resource	Text
File origin	Born digital
Access conditions	Open access Embargo expiration date: 2020-02-23
Terms of use
Repository	Repository of the Faculty of Science
Created on	2018-04-06 09:14:33

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