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undergraduate thesis
Potenciometrijski PVC tenzidni senzor obogaćen nanočesticama
Osijek: Josip Juraj Strossmayer University of Osijek, Department of Chemistry, 2016. urn:nbn:hr:182:700486
Harangozo, Dora
Josip Juraj Strossmayer University of Osijek
Department of Chemistry
Department of Analytical, Organic and Applied Chemistry

Cite this document

Harangozo, D. (2016). Potenciometrijski PVC tenzidni senzor obogaćen nanočesticama (Undergraduate thesis). Retrieved from https://urn.nsk.hr/urn:nbn:hr:182:700486

Harangozo, Dora. "Potenciometrijski PVC tenzidni senzor obogaćen nanočesticama." Undergraduate thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, 2016. https://urn.nsk.hr/urn:nbn:hr:182:700486

Harangozo, Dora. "Potenciometrijski PVC tenzidni senzor obogaćen nanočesticama." Undergraduate thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, 2016. https://urn.nsk.hr/urn:nbn:hr:182:700486

Harangozo, D. (2016). 'Potenciometrijski PVC tenzidni senzor obogaćen nanočesticama', Undergraduate thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, accessed 22 January 2021, https://urn.nsk.hr/urn:nbn:hr:182:700486

Harangozo D. Potenciometrijski PVC tenzidni senzor obogaćen nanočesticama [Undergraduate thesis]. Osijek: Josip Juraj Strossmayer University of Osijek, Department of Chemistry; 2016 [cited 2021 January 22] Available at: https://urn.nsk.hr/urn:nbn:hr:182:700486

D. Harangozo, "Potenciometrijski PVC tenzidni senzor obogaćen nanočesticama", Undergraduate thesis, Josip Juraj Strossmayer University of Osijek, Department of Chemistry, Osijek, 2016. Available at: https://urn.nsk.hr/urn:nbn:hr:182:700486

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Metadata
TitlePotenciometrijski PVC tenzidni senzor obogaćen nanočesticama
Title (english)Potentiometric PVC nanoparticles enriched surfactant sensor
AuthorDora Harangozo
MentorMilan Sak-Bosnar (mentor)
MentorNikola Sakač (mentor)
GranterJosip Juraj Strossmayer University of Osijek
Department of Chemistry
(Department of Analytical, Organic and Applied Chemistry)
Osijek
Defense date and country2016-07-28, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Analytic Chemistry
Abstract
Novi potenciometrijski senzor za anionske tenzide pripremljen je na osnovi višestjenčanih ugljikovih nanocjevčica (MWCNT) koji su upotrebljene za imobilizaciju 1,3-didecil-2-metilimidazol tetrafenilborat (DMI-TPB) ionskog para kao ionofora u membrani. Istraživani senzor pokazao je Nernstovski odziv za dodecilbenzensulfonat i dodecilsulfat. Odziv je prikazan unutar 8-10 sekundi za svaku deseterostruku promjenu koncentracije u rasponu od 1 x 10-7 M do 1 x 10-3 M. Granice detekcije za DBS i DS su 1 x 10-6 i 2 x 10-7 M. Senzor daje stabilan potenciometrijski odziv, te pokazuje zadovoljavajuću selektivnost za DS. Glavna primjena senzora je bila u otkrivanju završnih točaka u potenciometrijskim titracijama anionskih tenzida. Hyamine 1622, heksadeciltrimetilamonijev bromid i cetilpiridinijev klorid su testirani kao potencijalni kationski titranti i svi su dali analitički upotrebljive titracijske krivulje s dobro definiranim točkama ekvivalencije. Operativni životni vijek opisanog senzora je oko 3 mjeseca.
Abstract (english)
A new potentiometric anionic surfactant sensor was prepared based on multi-walled carbon nanotubes (MWCNTs) used for immobilisation of 1,3-didecyl-2-methylimidazolium tetraphenylborate (DMI-TPB) ion pair as ionophore in the membrane. The investigated sensor showed a Nernstian response for both dodecylbenzenesulphonate and dodecyl sulphate. It responded in 8-10 seconds for each ten-fold concentration change in the range of 1 x 10-7 M to 1 x 10-3 M. The detection limits for DBS and DS were 1 x 10-6 and 2 x 10-7 M, respectively. The sensor revealed a stable potentiometric response and exhibited satisfactory selectivity for DS. The main application of the sensor was in the end-point detection in potentiometric titrations of anionic surfactants. Hyamine 1622, hexadecyltrimethylammonium bromide and cetylpyridinium chloride were tested as potential cationic titrants, and all exhibited analytically usable titration curves with well-defined equivalence point. The operational life time of the sensor described amounted ca. 3 months.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:182:700486
ProjectNumber: IP-11-2013
Title: Primjena nanomaterijala u izradi potenciometrijskih tenzidnih senzora za primjenu u industriji i zaštiti okoliša
Acronym: NANOSENS
Leader: Milan Sak-Bosnar
Jurisdiction: Croatia
Funder: Hrvatska zaklada za znanost
Study programmeTitle: Chemistry
Study programme type: university
Study level: undergraduate
Academic / professional title: sveučilišni/a prvostupnik/prvostupnica (baccalaureus/baccalaurea) kemije (sveučilišni/a prvostupnik/prvostupnica (baccalaureus/baccalaurea) kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
RepositoryRepository of the Department of Chemistry, Osijek
Created on2017-01-04 08:22:56

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